In 1966's Alfie, Michael Caine plays the eponymous womaniser whose misogynistic lifestyle comes back to haunt him at the end of the film in the shape of a younger man in the bed of Shelley Winters' RubyPhotograph: Ronald Grant Archive'Frankly, my dear, I don't give a damn,' says Rhett Butler, played by Clark Gable, to Vivien Leigh's Scarlett O'Hara in 1939's Gone with the WindPhotograph: MGM/AllstarMarlon Brando plays the cruel and violent Stanley Kowalski in the 1951 film A Streetcar Named DesirePhotograph: Ronald Grant ArchiveRenée Zellweger's lead in Bridget Jones's Diary falls for ladies' man Daniel Cleaver, played by Hugh Grant, until she realises he is irredeemablePhotograph: Moviestore Collection/Rex FeaturesDon Juan is a wealthy, seductive libertine who devotes his life to seducing women, gambling and fighting. His legend has different endings, hell or redemption. Here, Mary Astor and John Barrymore appear in the 1926 film of his fictional story Photograph: Moviestore Collection/AlamyPhotograph: Moviestore collection Ltd / Alam/AlamyDanny Zuko, played by John Travolta, is a hip-swaying bad boy who ends up turning Olivia Newton-John's Sandy Olsson to the leather-jacketed dark side in 1978's GreasePhotograph: Cine Text/AllstarLaurence Olivier plays the tortured romantic Heathcliff whose passion destroys all. Pictured here with Merle Oberon's Cathy in 1939's version of Wuthering HeightsPhotograph: United Artists/AllstarTony Stark's first name is Playboy until he falls for Pepper Potts. Here Gwyneth Paltrow gets up close and personal with Robert Downey Jr in Iron Man 2Photograph: Marvel Studios/AllstarWe couldn't leave out Ian Fleming's James Bond. The sexiest incarnation has to have been Sean Connery. Here he is in 1962's Dr No, with Ursula Andress playing Honey RyderPhotograph: United Artists/AllstarMatt LeBlanc played the womanising Joey in the hit TV show Friends for a decade. Here he is trying his moves on Rachel, played by Jennifer Aniston, in the creatively titled episode, The One where Joey Dates Rachel. His smooth lines include: 'How you doin?' Photograph: C4Jon Hamm's Don Draper in Mad Men is a smooth-talking, chain-smoking, whiskey-swilling lothario of the highest orderPhotograph: Frank Ockenfels/AMC/LionsgateTroubled Jim Stark, played by James Dean, causes Natalie Wood's Judy a whole heap of trouble in 1955's Rebel Without A CausePhotograph: Everett Collection/Rex FeaturesIn like Flynn! Errol plays Robin Hood to perfection alongside his Maid Marian, Olivia de Havilland, in 1938's The Adventures Of Robin HoodPhotograph: Warner Bros/Allstar